Theory of chemical exchange in zero field NMR: Two‐site flips
نویسندگان
چکیده
منابع مشابه
Theory of chemical exchange in zero field NMR : Two - site flips
With conventional NMR of polycrystalline solids, broad and often featureless spectra are frequently obtained and the effects of some molecular motions are not readily observed. 1 The resolution and sensitivity of nuclear quadrupole resonance (NQR) and broadline NMR is often so low that only the rigid and rapid motional regimes can be studied. In the intermediate region, where the exchange rate ...
متن کاملZero-field NMR enhanced by parahydrogen in reversible exchange.
We have recently demonstrated that sensitive and chemically specific NMR spectra can be recorded in the absence of a magnetic field using hydrogenative parahydrogen induced polarization (PHIP) (1-3) and detection with an optical atomic magnetometer. Here, we show that non-hydrogenative parahydrogen-induced polarization (4-6) (NH-PHIP) can also dramatically enhance the sensitivity of zero-fiel...
متن کاملChemical analysis using J-coupling multiplets in zero-field NMR
Zero-field nuclear magnetic resonance (NMR) spectroscopy is emerging as a new, potentially portable, and cost-effective NMR modality with the ability to provide information-rich, high-resolution spectra. We present simple rules for analysis of zero-field NMR spectra based on first-order perturbation theory and the addition of angular momenta. These rules allow for the prediction of observed spe...
متن کاملHeteronuclear Zero-field Nmr
In zero-field NMR [ 1.21, a sample is subjected to a time-dependent magnetic field which cycles between a high value, Bo, and zero field. The B. field is useful for preparation and high-sensitivity detection of the spins. Evolution occurs for a variable time tl in zero field. This yields sharp crystal-like NMR spectra from polycrystalline samples, where ordinarily only powder patterns are obser...
متن کاملZero field NMR and NQR
Methods are described and demonstrated for detecting the coherent evolution of nuclear spin observables in zero magnetic field with the full sensitivity of high field NMR. The principle motivation is to provide a means of obtaining solid state spectra of the magnetic dipole and electric quadrupole interactions of disordered systems without the line broadening associated with random orientation ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1986
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.451722